How much CO2 and pollution comes from burning coal?

smoke and pollution come from stacks including coal power plants
Source: 123rf

It’s hard to visualize millions of tons of anything so let’s reduce the question to something simple and personal. How much CO2 and various types of pollution would be released from a coal plant if we powered a 100-watt lightbulb for a year? Let’s dig in.

A lightbulb - how much coal pollution is generated powering this bulb for a year?Our lightbulb will need 876 kilowatt hours of electricity for its year of operations. Assuming an average power plant efficiency of 37%, our lightbulb will require 800 pounds of coal (see: How much coal does it take to power a 100-watt lightbulb?).

So, for this hot tub sized pile of coal, what kind of unpleasant byproducts can we expect? Here’s a quick synopsis:

  • 3 pounds of sulfur dioxide
  • 1.67 pounds of nitrogen oxides
  • 122 pounds of coal ash
  • 0.64 ounces of uranium and thorium
  • 1,680 pounds of carbon dioxide (how can that be?)
  • 1/66th drop of mercury (nasty stuff)

For those of you that like to see the math or understand how more CO2 is created than the original weight of coal, you can follow along below.

3 pounds of sulfur dioxide pollution is emitted

Let’s start with sulfur dioxide (SO2), one of the main causes of acid rain. According to the EIA, the electric utility industry burned 851 million tons of coal in 2014. That same year, according to the EPA, the same utilities emitted about 3,195,000 tons of sulfur dioxide into the atmosphere. In other words, for every ton of coal burned, 0.00375 tons of SO2 is created.

     3,195,000 tons of SO2 
   ÷ 851 million tons of coal 
   = 0.00375 tons of SO2 per ton of coal

    2000 pounds per ton
  × 0.00375 tons of SO2 per ton of coal
  = 7.5 pounds of SO2

    0.4 tons of coal for our lightbulb
  × 7.5 pounds of SO2 per ton of coal
  = 3 pounds of SO2

By the way, coal-powered electricity is the largest source of SO2 by far, generating 64% of it in 2014.

1.67 pounds of nitrogen oxides are created

What about nitrogen oxides (NOx)? These pollutants create acid rain and smog. The same EPA report says that 1,776,000 tons of NOx were created by coal and the electric utilities. Applying the same math, our lightbulb will generate 1.67 pounds of nitrogen oxides.

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122 pounds of coal ash is left over

Coal ash is the solid byproduct left over after coal is burned. It is second only to trash as the largest source of waste material in the US. According to the EPA and the American Coal Ash Association, coal power plants created just under 130 million tons of ash in 2014. This means that every ton of coal we burn leaves 122 pounds of coal ash. Coal ash contains trace amounts of various toxic materials including chromium, arsenic, chlorine, chromium, lead, as well as uranium and thorium.

     129,684,142 tons of coal ash in 2014
   ÷ 851,000,000 tons of coal burned in 2014
   = 0.1523902961 tons of ash per ton of coal burned

     0.1523902961 pounds of ash per pound of coal burned (same ratio)
   × 800 pounds of coal to power a 100 watt lightbulb for a year
   = 121.91223688 pounds of ash created

In the US, most coal ash is captured and is no longer released into the air. Instead, it is often mixed with water and kept in nearby slurry ponds.

0.64 ounces of uranium and thorium are concentrated

The geologic processes that create coal concentrate a range of trace materials into these black rocks. Burning coal further concentrates these materials another 10-times. A study by the US Geologic Survey of 2,300 coal sites found the majority had concentrations of uranium between 1 and 4 parts per million. Similar results were found for thorium. Averaging this to 2.5 ppm and assuming a 10x concentration from burning, we can assume 25 ppm per element, leaving us with 50 ppm of radioactive materials per ton of coal.

A concentration of 50ppm in a ton of coal means about 0.1 pound, or 1.6 ounces, or 45 grams of radioactive materials. Therefore, the 800 pounds of coal required to power our lightbulb will leave behind 0.64 ounces of uranium and thorium, about the same weight as three quarters.

radioactive quarters

In some places, the concentrations can be 6-7 times higher – so high that at least one mining company is finding it cheaper to extract uranium from coal ash than uranium mines.

     0.0000050 (same as 50 ppm) concentration of U and Th per ton of coal
   × 2,000 pounds per ton
   × 16 ounces per pound
   = 1.6 ounces of U and Th per ton of coal

   = 0.64 ounces of U and Th in 800 pounds of coal

Just how dangerous is this radiation? Most research says not much at all. Remember, there is already a lot of natural background radiation and all the material from coal ash is caught and stored within the plant (at least in the US).  So, even if you live within a mile of a coal plant, you will only increase your exposure to radiation about 5% a year, less than an x-ray.

More interesting is that nuclear plants have far less radiation. A widely cited paper by Alex Gabbard, of Oakridge National Laboratory, found that the radioactivity outside a coal plant is up to 100-times higher than a nuclear plant. This is largely due to the safety regulations governing the nuclear industry (see: What are the risks of radiation from nuclear power plants?)

1,670 pounds of carbon dioxide

Coal’s most notorious byproduct is carbon dioxide (CO2). Every million BTUs released from burning coal releases an average of 208 pounds of CO2 (see note below). Since a ton of coal has 20.025 million BTUs, that means it creates 4,172 pounds of CO2 when it is burned. Running our 100-watt bulb for one year will produce 1,670 pounds of CO2.

But wait, how can 800 pounds of coal produce twice its weight in CO2? Another article from the EIA explains this in detail but, in short, it’s because the carbon atoms in coal are each combined with two atoms of oxygen from the air to form the CO2. In other words, the extra weight comes from pulling in material for the air.

At room temperature and pressure, 1670 pounds of CO2 would fill three 18-wheeler trucks.

Three trucks - the amount of space required to hold the CO2 from 800 pounds of burned coal

     20.025 million BTUs per ton 
   × 208.364 pounds per million BTUs
   = 4,172.4891 pounds of CO2 per ton of coal

   = 1,668.99564 pounds of CO2 per 800 pounds of coal

Note: this math is based on weighted average data. The specific amount of CO2 released varies with the kind of coal. US plants burn  45% bituminous, 47% subbituminous, and 7% lignite coal (source: EIA). They release 205.7, 214.3, and 215.4 pounds of CO2 per BTU, respectively (source: EIA). The weighted average is 208.364.

1/66th drop of mercury 

OK, this one will take some work but it’s important to do because some forms of mercury can be really nasty stuff. Coal plants account for half of all human-released mercury (source: EPA). Mercury is a heavy metal and a potent neurotoxicant. The type of mercury in thermometers carries some health risks but when it is released into the atmosphere, it combines with other elements and can easily create far more toxic variants.

There is a widely told story of a researcher, Karen Wetterhahn, who tragically died after only a drop or two of a particularly lethal compound of mercury fell on her hand. Despite wearing latex gloves, the mercury seeped through to her skin in a matter of seconds and she later died. This story is meant to be illustrative and drive home the health risks of mercury. It is not a scientific study or safety evaluation. But, if you want to look at the math and see how it works for yourself, read on…

An EPA report called The National Emissions Inventory (page 2-30) estimates that 22.9 tons of mercury were released from coal-fired power plants in 2014 (note that other environmental studies put this number 2-4 times higher). This means that 0.00000002809816 tons of mercury, or 0.00005619632 pounds of mercury, or 0.02549065075 grams of mercury comes from each ton of coal.

     22.9 tons of mercury 
   ÷ 851 million tons of coal 
   = 0.00000002809816 tons of mercury per ton of coal

     0.00000002809816 tons 
   × 2000 pounds per ton
   = 0.00005619632 pounds of mercury per ton of coal

     0.00005619632 pounds
   × 453.6 grams per pound
   = 0.02549065075 grams of mercury per ton of coal

Since pharmacists define 0.05 milliliters of liquid as a drop and 1 gram of mercury fills 0.073888 milliliters (mercury conversion), one ton of coal contains 0.03766906406 drops of mercury.

      0.02549065075 grams of mercury per ton of coal
    × 0.073888 milliliters per gram
    = 0.001883453203 milliliters of mercury per ton of coal

      0.001883453203 milliliters of mercury per ton of coal
    ÷ 0.05 milliliters per drop 
    = 0.03766906406 drops of mercury per ton of coal

Our lightbulb takes 800 pounds, or 0.4 tons of coal, which means burning it creates 0.01506762562 drops of mercury or rounding it a bit, 1/66th of a drop.

     0.02549065075 drops of mercury per ton of coal
   × 0.4 tons of coal to power a 100 watt lightbulb for a year 
   = 0.01506762562 drops of mercury per 100 watt lightbulb per year

     1 ÷ 0.01506762562 drops = 66.36 or 1/66th

Additional Reading

Caveats

Note: There are numerous sources of information on the topic of coal byproducts. The math is shown here to help explain how our numbers were derived but it is inevitable that other approaches will yield different results. If you find a glaring mistake, please let us know in the comments below.

Also note: we use the US government data wherever possible. Many environmental groups do their own studies and find pollution is often worse than reported by the government. Our goal here is to bring as many people as possible into these conversations so we avoid using data that could be dismissed as aggressive.

12 thoughts on “How much CO2 and pollution comes from burning coal?

  1. You might want to add a paragraph on how much uranium is released when coal is burned. I read an article that claimed it was more significant than the amounts released by nuclear power plants.

    1. Great suggestion! A section on nuclear has been added. There was very little reliable data to pull from but the final amount was higher than I expected.

  2. on the other hand SO2 has actually cooling effect for Earth’s atmosphere, due to light reflection back in space (as well as hard particles)… so not that straight forward as well

  3. Looking to the huge consumption of coal and continuously increasing trend power generation, it mast be made mandatory for government bodies to check the Radiation level at every ash pond regularly.

  4. we need more natural CO2 scurber which is none other than TREES. We also have to estimate how much a single tree contributes in scurbing CO2.

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